Additional Field Placement
Placement is available for Additional fields.
Before billing form
Places the field before WooCommerce billing fields.
After billing form
Places the field after the billing field group.
Before order notes
Places the field immediately before the order-notes area.
After order notes
Places the field after the order-notes area.
Recommendation
Choose the location that matches the meaning of the field so customers encounter the question at the right stage of checkout.